John A. Venables
Cambridge University Press (2000)
It seems to be "common sense" that the equation should have the
g* on the the other side, since by depositing A on B, we are
replacing the (free) energy gB by
gA. If we take into account the interface energy
g*, thinking of it as a positive but small energy, then indeed we
should have gA + g* <
gB; the free energy must go down to be consistent with
layer growth. This statement occurs in our review article (Venables et al. 1984) on
page 405 in equation 1.3, correctly. These statements are traceable directly to the review
by Kern et al. (1979), where they discuss this topic in much more detail, considering
several sub-cases and possible mechanisms. You may however note in passing that figure 1 in
our review was garbled, with inconsistencies between
the text, figure captions and the figure.
Figure 5.3 derives from my more recent review (Venables 1994, figure 1) where I was wishing
to compare compactly both the layer and the SK growth mode in what is here figure 5.3(a).
The point here is that layer growth is definitely favored if
gA < gB.
However if the interface energy builds up as the layers are deposited, then at some stage a
switch to islands can occur; this is the SK mode. But figure 5.3(b) illustrates the growth
of islands of B on A, not A on B. So in this case the equation on page 146 describes
island growth of B on A:
gB + g* >
gA; the interest in considering A on B, and then B on A,
arises from the role of these two different interfaces in multilayers.
Just to prove that this topic has a jinx on it, there was also an error in the 1994 review
text description of what is here figure 5.3(a). But the bottom line is that the statement on
page 146 is incorrect for describing layer growth of A on B; it should be
gA + g* <
gB. Thankyou for pointing out this error.
New references for section 5.1
Book contents,
Introduction/ ordering information or my
Home page.
Section 5.1: Introduction: growth modes and nucleation barriers
In section 5.1.3 a point of confusion has been noted by some students about the
relation between a) the statement on page 146 starting "When we deposit material A on B,
we get layer growth if gA <
gB + g*, where
g* is the interface energy, and vice versa for island growth",
and b) the illustrations of figure 5.3(a) and (b) on page 147. This addendum discusses
this confusion in more detail so that you can become really confused...
Latest version 4th March 2001.