PHY 598 (Venables) Sect 2.1

Notes for PHY 598 Sect 2.1 (Venables)

© Arizona Board of Regents for Arizona State University and John A. Venables

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Lecture notes by John A. Venables. Notes revised for Spring 2005: Latest version 6 February 2005

2. Surfaces in Vacuum: Ultrahigh Vacuum Techniques

Refs: Prutton, Introduction, p5-10 and Luth, Panel I, p6-17 give an introduction to the 'feel' of surface science apparatus and experiments. Woodruff and Delchar devote Chap 1 to this topic amongst others. It is probably not possible to do justice to this topic in a book: it would take too much space, but Luth has made a brave attempt within the allotted number of pages. More detailed books exist, which you may wish to look at, including A. Roth, Vacuum Technology (3rd Edn, 1990), and J.F. O'Hanlon, A Users Guide to Vacuum Technology (1989); I'd be interested to know which book of this type you found actually useful, except for reference.

Manufacturers’ catalogues are useful, assuming that you know that they are attempting to get you to buy something (in the long run). Although all such catalogues provide detailed information about the products, the Leybold-Heraeus catalogue has traditionally included a tutorial section which helps one understand what the products are doing, and what choices the purchaser needs to make. Relatively small performance improvements in vacuum components can cause quite a commercial stir. So one always needs to consider what the latest model, or flavor of the month, is really doing.

I will emphasize the physical principles on which these devices are based, in the hope that these do not change too fast. Also, you may not have to buy anything. Surface Science is now a fairly mature discipline, so there will be kit lying around. But you need to know what it can, and cannot, do. In practice there is no substitute for visiting, and then working in, a Surface Science laboratory, each of which will have its own practices and recipes. So we will arrange a lab visit for those of you not already working in this environment, before too long.

2.1 Kinetic Theory Concepts

  • Arrival Rate of Atoms at a Surface
  • The Molecular Density
  • Note added 13 may '02: There is a typographic error in the second equation for n (below), which should have (p/T) on the right hand side, not /T. Thanks to Karsten Pohl for spotting this mistake.

  • The Mean Free Path
  • The Monolayer Arrival Time

  • Continue to section 2.2

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